although a lot of substances can dissolve in water there are many that are insoluble in water. most of those substances are non polar in nature. non polar substances have elements in them have similar electronegatives and those elements are symmetrically distributed in the compound.
here are some helpful links for aqueous solutions.
http://chemistry.bd.psu.edu/jircitano/aqueous.html
http://chemwiki.ucdavis.edu/Wikitexts/United_Arab_Emirates_University/UAEU_CHEM_111/Full_Chapters/Full_Chapter_04._Reactions_in_Aqueous_Solution
http://chemwiki.ucdavis.edu/Inorganic_Chemistry/Reactions_in_Aqueous_Solutions/Unique_Features_of_Aqueous_Solutions
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